WebExpanded octet occurs when an atom is able to have more than 8 valence electrons. For example, in SO₃, the sulfur atom forms 6 covalent bonds, hence it has 12 valence electrons. Expansion of octet is possible only from Period 3 elements onwards, due to the presence of low-lying empty d orbitals that can accommodate the extra electrons. WebNov 2, 2024 · Atoms in these periods may follow the octet rule, but there are conditions where they can expand their valence shells to accommodate more than eight electrons. Sulfur and phosphorus are common examples of this behavior. Sulfur can follow the octet rule as in the molecule SF2. Each atom is surrounded by eight electrons.
Solved 3. Which of the molecules below contain an atom with
WebAug 3, 2024 · Molecules, where some atoms have fewer than eight electrons, are called electron deficient. Too Many Electrons: Expanded Octets . Todd Helmenstine. Elements in periods greater than period 3 on the periodic table have a d orbital available with the same energy quantum number. http://guweb2.gonzaga.edu/faculty/cronk/CHEM101pub/Lewis_structures_II.html man wires his talking wall fish to alexa
Violations of the Octet Rule - Chemistry LibreTexts - The Bond …
WebAn element from Period 3 and belowwill be able to expand octet by making use of its energetically accessible, or low lying d-subshell for bonding. This means only Period 2 elements such as C, N, O and F cannot expand octet and have to obey octet rule. Which elements can have an expanded octet Why? WebWhen an atom can have more than 8 valence electrons, it forms an expanded octet. Arsenic is bonded to 5 chlorine atoms and has an electronic configuration of [Ar] 3d¹⁰ 4s² 4p³. To create 5 bonds with chlorine atoms, it has to utilize its d-orbitals, allowing it to fit more than 8 electrons in its valence shell. WebOct 7, 2024 · Species with Expanded Octets . Examples of molecules with more than an octet of electrons are phosphorus pentafluoride (PF 5) and sulfur hexafluoride (SF 6). … man wipes brow